Revision 10 as of 12:06PM, May 29, 2011

Let us consider the following question.

Inlined image: Hole.png

What are the correct responses to this question? It depends.

In this question, the expected answer is probably C. This is what I call a simple-minded answer.

This is an OK answer. It is not an incorrect answer, but it is just a simple-minded answer, based on a simple-minded definition of a hole (which this on-line activity is limited to). It is like when we have a collection of electrons in a metal such as Na or Al, we call them a collection of holes. Or, when we have 6 electrons in the 3d shell of $Fe^{2+}$ ions, we can call them 4 holes instead, as it takes 10 electrons to fill the 3d shell. This is a sometimes-useful general view.

In this view, as the hole is just the absence of the electron, it may not be viewed as fundamental. Also, microscopically, hole is not really free (and neither is electron). Therefore, A and B are not good choices.

OK, but what if we go beyond this simple minded view? Let us take a sophisticated point of view, which I advertised in this course. This is a better view. In such a view, all of A,B,C can be answers.

Recall that the more useful meaning of holes in a semiconductor is the absence of electrons on top of the valence band, which is almost full. This is generally what we mean by holes in a semiconductor, and it is for a good reason. In such a case, a hole gains a fundamental nature, since the effective mass becomes positive only in the language of a hole. Such a hole is fundamentally distinguishable from an electron. The signs of the Hall coefficient ($R_H$) and thermopower are examples which can clearly distinguish between an electron and a hole. In this view, a hole is fundamentally distinguishable from an electron by experiment. So, A is a good choice (see more discussion in the last two paragraphs below).

As regards the choice of B, this is also a good choice in this sophisticated point of view. Let us ask this question. When we talk of an electron or a hole in a semiconductor, what mass do we associate with it? The answer is the effective mass! If one takes this point of view, then, what we are saying is that an electron or a hole in a semiconductor is quite a different particle from the bare electron that we normally speak of. And, such an electron or a hole moves completely independent of atoms, since the effect of the bare-electron—atom or bare-hole—atom interaction is already included in the effective mass.

[Optional reading from this point on.] Note that in this sophisticated view, we can easily understand why the positron is viewed as a fundamental particle. Also, you might note that even if we consider a bare electron as a free electron, the modern view (QED) is that what we call a free electron is itself a result of a complex interaction of electrons and photons. In this fundamental view, every fundamental particle is simply an emergent particle from complex interactions. Such an emergence particle will be characterized by an effective mass etc., which we simply call the electron mass (0.511 MeV)! In the case of the electron, the magnetic moment of the electron is such an effective quantity too, which Feynman's QED theory famously produced with high accuracy.

The formal name of this sophisticated point of view is the renormalization group theory, a quite fundamental subject in all of physics.